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It's possible that the app loads Python dynamically. If you are able to get a Python shell in the app, try this:
import sys
print(sys.executable)
Using that executable might work, but there's no real guarantee that there is a regular Python installation in there.
If not, you may still be able to debug Python code running in the app as described here:
https://wingware.com/doc/debug/debugging-externally-launched-code